ASTM A335 Seamless Ferritic Alloy Steel Pipes for High-Temperature Service

No.ASTM A335
ASTM A335 seamless ferritic alloy steel pipes are designed for high-temperature piping systems requiring elevated-temperature strength and alloy-steel performance.
Available in grades including P5, P9, P11, P22, P91 and P92, these pipes are widely specified for power generation, boiler piping, steam lines and high-temperature process systems.
ASTM A335/A335M seamless ferritic alloy steel pipe
Designed for high-temperature service
Low- and intermediate-alloy steel grades
Common grades include P5, P9, P11, P22, P91 and P92
Suitable for bending, flanging and similar forming operations
Suitable for fusion welding
Grade-specific chemical composition and mechanical properties
Grade-specific heat treatment
Hydrostatic testing
Nondestructive examination of each pipe
Supplementary testing available when specified
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Description

Product Overview

ASTM A335 is the standard specification for seamless ferritic alloy steel pipe intended for high-temperature service.

Specified Standard Edition: ASTM A335

Standard Title: Standard Specification for Seamless Ferritic Alloy-Steel Pipe for High-Temperature Service

The specification covers both nominal-wall and minimum-wall seamless alloy steel pipe.

ASTM A335 pipes are required to be suitable for bending, flanging and similar forming operations, as well as fusion welding.

Material selection depends on the design, service conditions, required mechanical properties and high-temperature characteristics.

ASTM A335 Grades

ASTM A335 covers multiple ferritic alloy steel grades. Commonly specified grades include:

P5 / P9 / P11 / P22 / P91 / P92

Grade Material Description & Typical Service
P5 / P9 Higher-chromium alloy grades used in high-temperature process and refinery piping where the applicable material specification requires these grades
P11 Cr-Mo alloy steel commonly specified for high-temperature pressure piping and steam service
P22 Higher Cr-Mo alloy steel widely used for elevated-temperature steam and process piping
P91 Modified 9Cr-1Mo-V-Nb steel developed for high-temperature service requiring higher strength than conventional Cr-Mo grades
P92 Advanced 9Cr-class creep-strength-enhanced ferritic steel used in demanding high-temperature power and steam applications

Other ASTM A335 grades can be reviewed according to the project specification.

The required grade should be selected according to the applicable piping design code, design temperature, design pressure, service medium and project material specification.

Chemical Composition

ASTM A335 defines separate chemical-composition requirements for each grade.

Grade Principal Alloy System
P5 Approximately 5Cr-Mo alloy system
P9 Approximately 9Cr-Mo alloy system
P11 Cr-Mo alloy steel
P22 Approximately 2¼Cr-1Mo alloy system
P91 Modified 9Cr-1Mo steel with controlled V, Nb and N additions
P92 Modified 9Cr steel with Mo-W-V-Nb alloying additions

Because ASTM A335 includes multiple alloy systems, chemical composition should be verified against the exact ordered grade rather than applying one composition range to the complete A335 product family.

Mechanical Properties

Mechanical-property requirements are grade-specific. ASTM A335 specifies requirements including:

  • Tensile strength
  • Yield strength
  • Elongation
  • Hardness

Different grades have different strength and hardness requirements.

P11, P22 and the higher-strength P91/P92 grades should therefore be treated as separate materials during engineering selection, purchasing and fabrication.

The required mechanical properties are verified against the exact ASTM A335 grade and applicable wall thickness.

Heat Treatment

Heat treatment is a critical requirement for ASTM A335 alloy steel pipe and varies by grade.

Depending on the specified grade, applicable heat-treatment routes include:

  • Full or isothermal annealing
  • Normalizing
  • Normalizing and tempering
  • Quenching and tempering

Higher-alloy and creep-strength-enhanced grades such as P91 and P92 require tightly controlled grade-specific heat treatment.

The required delivery condition should be confirmed from the ordered ASTM A335 grade and project specification rather than applying one common heat treatment to all A335 materials.

Hydrostatic Testing

Each length of ASTM A335 pipe is subject to hydrostatic testing in accordance with the applicable specification requirements.

Where project specifications impose additional pressure-test requirements, these should be stated at the enquiry and order stage.

Nondestructive Examination

ASTM A335 requires each pipe to be examined by a nondestructive examination method in accordance with the applicable requirements.

The available examination method depends on pipe dimensions, specification requirements and the applicable referenced practice.

Project requirements for the following should be identified during the RFQ stage where applicable:

  • Ultrasonic examination
  • Eddy-current examination
  • Flux-leakage examination
  • Additional NDE

Mechanical Testing

Applicable mechanical tests include:

  • Transverse or longitudinal tension test
  • Flattening test
  • Hardness test
  • Bend test where applicable

Test requirements depend on pipe dimensions and the applicable ASTM A335 provisions.

Supplementary Requirements

ASTM A335 includes optional supplementary requirements that may be specified by the purchaser. These provide additional testing or quality requirements beyond the base specification.

Where supplementary requirements are required, the applicable designation and required test frequency should be stated in the purchase order.

This is particularly important for power-generation, critical steam piping and project-controlled pressure-piping applications.

Pipe Dimensions & Ordering

ASTM A335 is a material specification rather than a single fixed-dimensional product standard.

Pipe dimensions are commonly ordered using either of the following formats:

Ordering Method Required Dimensions
Nominal Pipe Size NPS + Schedule
Specified Dimensions Outside Diameter + Wall Thickness

The purchase order should clearly identify whether nominal-wall or minimum-wall pipe is required.

Dimensional requirements and tolerances should follow the applicable ASTM general requirements and project specification.

ASTM A335 vs ASTM A213

ASTM A335 and ASTM A213 can include similar Cr-Mo and high-temperature alloy systems, but they cover different product forms and applications.

Comparison ASTM A335 ASTM A213
Product Form Seamless ferritic alloy steel pipe Seamless ferritic and austenitic alloy steel tubes
Primary Service High-temperature service Boiler, superheater and heat exchanger service
Typical Grade Designations P11 / P22 / P91 T11 / T22 / T91

The specifications should not be treated as interchangeable solely because the alloy systems appear similar.

FYN Manufacturing Capability

Parameter Capability
Product Form Seamless Alloy Steel Pipe
Typical Grades P5 / P9 / P11 / P22 / P91 / P92
Manufacturing Cold Drawn / Cold Rolled
Outside Diameter 6–114 mm
Wall Thickness 0.8–25 mm
Length Up to 40 m
Heat Treatment Grade-Specific
Inspection Hydrostatic / UT / ET as specified
Documentation MTC / EN 10204 / TPI as required
Third-Party Inspection Available upon request
Custom Sizes Subject to grade and technical review
MOQ According to grade, dimensions and production requirements

ASTM A335 standard requirements and FYN manufacturing capability are stated separately.

Actual grade availability and manufacturable dimensions are confirmed according to the required grade, outside diameter, wall thickness, length, heat treatment, inspection and quantity.

Typical Applications

ASTM A335 seamless alloy steel pipe is primarily used in high-temperature pressure piping systems.

Main Steam Piping

P11, P22, P91 and P92 are among the alloy grades used in steam piping systems where the selected material meets the applicable design conditions and piping code.

Boiler & Power Plant Piping

For high-temperature pressure piping connecting boilers, superheaters, reheaters, headers and associated steam-system equipment.

Superheater & Reheater Piping

For high-temperature steam transfer outside the heat-transfer tube sections where ASTM A335 pipe is specified by the piping design.

Petrochemical & Refinery Piping

P5, P9 and other Cr-Mo grades are used in high-temperature process piping where the project material specification requires ASTM A335 alloy steel pipe.

Chemical & Process Plants

For high-temperature pressure piping carrying steam or process fluids under conditions compatible with the selected A335 grade.

Industries Served

  • Thermal Power Generation
  • Industrial Boilers
  • Petrochemical & Refining
  • Chemical Processing
  • Power Plant Construction
  • Steam & Energy Systems
  • High-Temperature Process Plants
  • Pressure Piping Fabrication

Documentation & Traceability

Available documentation can include:

  • Mill Test Certificate
  • Heat / lot traceability
  • Chemical analysis results
  • Mechanical test results
  • Hardness results
  • Heat-treatment records
  • Hydrostatic test records
  • NDE records
  • Dimensional inspection records
  • Material identification
  • EN 10204 documentation as specified
  • Third-party inspection reports when arranged

Documentation requirements should be specified during the RFQ stage.

Packing & Delivery

Typical export packing includes:

  • Steel bundle packing
  • Identification tags
  • Pipe-end protection
  • Rust-prevention protection when required
  • Seaworthy export packing
  • Project-specific marking and packing

End preparation can be reviewed according to the piping fabrication requirement.

Long-length pipes may require special packing and transportation arrangements.

Production lead time depends on grade, dimensions, quantity, heat treatment and inspection requirements.

Ordering Information

For quotation, please specify:

ASTM A335/A335M + Grade + NPS / OD + Schedule / Wall Thickness + Length + Quantity

Required Information Details
Standard ASTM A335/A335M
Grade P5 / P9 / P11 / P22 / P91 / P92 or other specified grade
Pipe Size NPS or outside diameter
Wall Thickness Schedule or specified wall thickness
Wall Basis Nominal wall or minimum wall
Length Required pipe length
Quantity Required order quantity
Heat Treatment Required condition, if specified
Testing Hydrostatic / NDE requirements
Supplementary Requirements Applicable designation and test frequency, if required
Material Designation ASTM or ASME designation required by the project
End Preparation Required end preparation
Documentation Inspection documentation requirements
Third-Party Inspection If required
Delivery Delivery destination

For project enquiries, send your piping material specification, MTO, drawing or technical specification for technical review.

Request a Quotation

For an accurate quotation, please send your required grade, NPS or outside diameter, schedule or wall thickness, length and quantity.

For power-generation and high-temperature piping projects, please also provide the applicable piping material specification, supplementary requirements, NDE requirements and inspection documentation requirements.

For P91 / P92 projects, include the complete material and heat-treatment requirements from the project specification for technical review.